Showing posts with label powdercoating. Show all posts
Showing posts with label powdercoating. Show all posts

11/11/2019

Surface Preparations For Powder Coating



Surface Preparations For Powder Coating


Surface preparation is one of the most important factors in powder coatings as well as liquid coatings and almost all coatings.

Surface preparation is often expressed as surface pretreatment or surface treatment.

Surface pretreatment for painting can be approached in two main ways.


1. Surface cleanliness


When we think about the surface preparation, there is a famous well-known standard for it. It is ISO 8501(Preparation of steel substrates before application of paints and related products - Visual assessment of surface cleanliness).

And its title said 'surface cleanliness'. Because this is an important factor in surface preparation, and most surface preparation methods are used to make the surface clean.


2. Improving Adhesion


In the painting preparation process, the surface pre-treatment through the cleaning or post-cleaning process usually involves a process to increase the adhesion between the coating and the substrate. One way to increase adhesion is to increase the surface area physically and chemically, such as by shot/grit blasting or conversion coating.


Anyway, surface treatment for painting determines about 60-80% of the paint quality.

Spray type process line of Surface Preparation
Spray type process line of Surface Preparation


Let's take a look at surface pretreatment methods that are mainly used in powder coating.



1. Shot/Grit Blasting


Abrasive blasting is a more appropriate and broad term, but in the field, sandblasting and shot blasting are also used.

Short or grit is a term that describes the form of media used for blasting.

Sandblasting use sand to blast, so it is called sandblasting.

Abrasive blasting is an effective method that has been used for a long time.

The media particles are collided with the surface of the material by using air pressure or centrifugal force to remove rust or foreign substances on the surface. And a profile is formed on the surface due to the collision, which increases the surface area and thereby affects the adhesion.


2. Degrease


In powder coating and liquid coating field, the surface is prepared by just removing foreign substances such as oil and grease on the surface with solvent or detergent, to be coated.

Most of the metal is contaminated with oil because the processing oil or lubricating oil is usually used when the metal goes through the forming process.

Such the oils can decrease the adhesion between the surface of the material and the coating film, or cause defects such as cratering.

Degreasing methods includes using alkaline detergent, acid solution and solvent.


3. Conversion Coating


Conversion coating is slightly difficult to get the concept of it. But it is easy if you think of the plating on the material surface with chemical reaction. The method combines the surface of the material with other metals to improve the coating adhesion and corrosion resistance.

Conversion coating is largely divided into Phsphate and Chromate. Phosphating conversion coating is mainly used for iron(steel) materials, and chromate is used for aluminum(alloy) materials.

In recent years, various conversion coating agents such as Zirconium and non-chrome have come out, and these various conversion coating agents are being developed to reduce environmental pollution, improve adhesion and corrosion resistance.


4. Acid Cleaning


Acid treatment, called pickling, is a method of removing rust or mill scale from surfaces using a strong acid solution.



The preparation methods is used alone or also in combination.

For example, the surface preparation process for the automotive wheel is simply like below.


Blasting -> Degreasing -> Rinsing -> Acid Cleaning -> Rinsing -> Conversion Coating -> Rinsing -> DI water Rinsing


Continuously surface preparation methods are applied in various ways according to environmental regulations, materials to be coated, and pretreatment efficiency, and are being developed in various ways.
And we will see them in detail later.


LINK: Korean Version of This Post([도장 전처리]분체도장에 주로 사용되는 전처리방법들)

10/31/2019

TGIC Hazards Used as Powder Coating Curing Agent


Harmful Substances in Our Lives that We Do Not Know Well: TGIC (triglycidyl isocyanurate)





Mutagen! Organ Damage!
There are many harmful substances that we use but we do not know well in our lives.

Among them, we will learn about Triglycidyl Isocyanurate (TGIC) which is mainly used as a hardener.
TGIC is a raw material that is widely used as a curing agent in powder coatings using polyester resins.
The hardener is combined with the resin, which plays a role in the performance of the paint as a film.

There are two types of hardeners used in polyester resin powder coatings, a TGIC-free type hardener and a TGIC type hardener.

Powder coatings of polyester resins are wildly used in


  • For indoor, industrial machines, interiors, furniture, home appliances, office furniture, electrical appliances, etc.
  • For outdoor use, mobile parts, achitectural material such as fasade and window frames, electric control box, outdoor air-conditioner unit, etc.



Acute toxicity(GHS pictogram)

So now on, let's take a closer look at the harmfulness of TGIC.


  • TGIC can be absorbed by the body through the skin. In addition, it can be introduced through the mouth or breath, and dust containing TGIC is often introduced into the body through breathing.
  • If swallowed or inholed TGIC, it could damage the lungs, kidneys and digestive system.
  • The more contact with TGIC, the more sensitive the body is to TGIC.
  • TGIC can cause serious eye damage.
  • Animal testing has shown that TGIC can cause genetic modifications.
  • Blisters, itching, and swelling were observed in workers who used powder coatings or hardeners containing TGIC, asthma and leukocytosis in exposed powder spray workers, and atopic symptoms in exposed skin.
  • Human tests of cancer patients showed toxic symptoms such as decreased spinal cord activity (blood production), dizziness, vomiting, white blood cell reduction, and partial hair loss.



There is still a lack of long-term testing for the effects of TGIC on the human body. So in addition to the hazards mentioned above, there may be more serious effects.

health hazard
Health Hazard(GHS pictogram)

So please be aware of the following points when handling TGIC.


Where powder coatings containing TGIC are used,

  1. Paint booths with limited access should be used.
  2. Vacuums / suction cleaners should be used for cleaning to minimize dust.
  3. If you use a powder coating with TGIC, you will need to wear personal protective equipment such as gloves, dustproof clothing, safety glasses and a dust mask.
  4. Personal protective equipment must be worn in all processes of handling powdercoatings that containing TGIC.

To deal with TGIC as a raw material,

  1. Vacuums cleaners should be used to minimize dust generation.
  2. The process of handling raw materials must be designed to be sealed and automated as possible to minimize human access.
  3. Dust collectors / suction facilities are provided throughout the workplace so that dust can be removed immediately.
Wherever TGIC is handled, safety training for personnel, training to wear personal protective equipment and provision of personal protective equipment should be provided and done.

TGIC should be more careful as its toxicity persists even after commercialization with raw materials.

Products containing TGIC are prohibited for use in some parts of China as well as in Europe.

Many countries are aware of the toxicity of TGIC, and regulations on safety training and dust collection facilities for workers are being implemented. Companies that used products containing TGIC are increasingly demanding TGIC-free products.